Chiral Luminescence, 2 Volumes From Molecules to Materials and Devices

Comprehensive resource illustrating the latest stage and development of chiral luminescence in science and technology, from fundamentals to applications

Chiral Luminescence imparts a comprehensive understanding for chiral materials bearing circularly polarized luminescence (CPL) functions, including molecules, oligomers, polymers, chiral metal organic complexes, and chiral biochemical materials, with guidance on how to promote and control this kind of luminescence towards the development of advanced photonic materials and devices such as chiroptical and electronic devices, next-generation displays, and others.

The book covers detailed information on the molecular design, synthesis, and polymerization methods of chiral luminescent materials, the evaluation of chiroptical properties represented by CPL, novel spectroscopic instruments and techniques, the fabrication of chiral luminescent devices such CPL-OLED, a theoretical evaluation, and potential applications.

With insight from leading academics and industrial researchers in the field, Chiral Luminescence includes information on:

• Optical resolution and chiroptical properties of partially overlapping carbazolophanes and developments in CPL research using cyclodextrins
• Synthesis and chiroptical properties of helical, conjugated polymers and twisted molecules, and chiroptical and magnetooptical properties of porphyrin compounds
• Principles of CPL measurement systems and advances in measurement methods, and intense and sign-invertible CPL
• Development of organic light-emitting diodes using aggregation-induced enhanced CPL perylene diimides
• Binding constants as fundamental physical properties for quantitative treatments of sensing processes in supramolecular systems

Providing far-reaching coverage of chiral luminescence and its many applications, Chiral Luminescence is a must-read resource for a variety of chemists and engineers who wish to understand the state-of-the-art development in this optical science.

VOLUME 1:

Section I Molecules

01 Synthesis and Properties of Circularly Polarized Luminescence-Active Molecules based on Binaphthyl Skeleton

02 An Approach for the Qualitative Understanding of Electronic and Magnetic Transition Moments Aiming at the Design of CPL Chromophore Having Enhanced Chiroptical Properties

03 Optical Resolution and Chiroptical Properties of Partially-Overlapped Carbazolophanes

04 Circularly Polarized Luminescence in Stereogenic Pi-Conjugated Macrocycles

05 Developments in Circularly Polarized Luminescence Research Employing Cyclodextrins

06 Circularly Polarized Luminescence based on Chiral AIEgens

07 Planar Chiral [2.2]Paracyclophane: Excellent Circularly Polarized Luminescence Emitters

08 Nanometrical Helical Structures as Platform to Induce Chiroptical Properties to Achiral Components

Section II Oligomers and Polymers

09 Synthesis and Chiroptical Properties of Helically Stacked Conjugated Polymers

10 Synthesis and Chiroptical Properties of Helical, Conjugated Polymers, and Twisted Molecules

11 Chiroptical and Magneto-optical Properties of Porphyrin Compounds

12 CPL Emission from The Photo-Excited Parallel-Oriented Aryl/Aryl Dimer

13 Synthesis, Control of Higher-Order Structures, and Optical Properties of Platinum-Containing Poly(aryleneethynylene)s and Related Compounds

14 Chiroptical Supramolecular Assemblies

15 Circularly Polarized Luminescence (CPL) in Helically Assembled Pyrene Pi-Stacks on RNA Duplex

16 Circularly Polarized Luminescence of Helical Network Polymers Synthesized in Chiral Liquid Crystals

17 Ultraweak Intermolecular Interactions in Chirogenesis from Non-Charged CPL-/CD- Silent Molecules, Oligomers, and Polymers Endowed with Noncharged Chiral Terpenes, Mono-/Polysaccharides, and Helical Polysilanes

Section III Coordination Compounds

18 Circularly Polarized Luminescence Induced by an External Magnetic Field: Magnetic Circularly Polarized Luminescence

19 Phosphorescent Organometallic Complexes Aimed at Fabrication of Electroluminescent Devices

VOLUME 2:

20 Enhancement of Circularly Polarized Luminescence in the Condensed Molecules and Coordination Complexes

21 Control of the Emission and Chiroptical Properties of Helicene Derivatives

22 Recent Advances on CP-OLEDs and CPL-Active Materials of Chiral Metal-Containing Complexes

23 Evolving Fluorophores into Circularly Polarized Luminophores with Chiral Naphthalene Dimers and Tetramers

24 Polarized Luminescence of Lanthanide Coordination Compounds

25 CPL in Chiral Metal Nanoclusters

26 Circularly Polarized Luminescence Chromophores Based on Metal Complexes

Section IV Theory and Spectroscopy

27 Recent Advancement of Circularly Polarized Luminescence of Helicenes

28 Systematic Investigation on CPL Properties of Various Chiral Motifs through Theoretical Calculation

29 Principles of CPL Measurement Systems and Advances in Measurement Methods

30 Using Chiroptical Spectroscopy to Gain Unique Information about the Solid-State

31 Circularly Polarized Luminescence for Molecular Systems of Increasing Complexity

32 Luminescence and CPL Spectra of d10 Metal Complexes

Section V Devices for Application

33 Development of Organic Light-Emitting Diodes using Aggregation-Induced Enhanced Circularly Polarized Luminescent Perylene Diimides

34 Chiroptical Properties Enhancement of Chiral Eu(III) Complex in Association with Ionic Materials such as DNA Toward Device Application

35 Circularly Polarized Luminescence Materials and Their Organic Light-emitting Device Performances

36 Intense and Sign-Invertible Circularly Polarized Luminescence

37 Direct Emission of Circularly Polarized Light from Twisted Structure of Mesogenic Luminophores and

Improvement of OLEDs

38 Binding Constants as Fundamental Physical Properties for Quantitative Treatments of Sensing Processes in Supramolecular Systems

Kazuo Akagi is an Eminent Research Professor, Research Organization of Science and Technology at Ritsumeikan University in Shiga, Japan, and a Professor Emeritus of Kyoto University and University of Tsukuba, Japan. After graduating from Kyoto University, he spent most of his career working for University of Tsukuba and Kyoto University before taking up his present appointment at Ritsumeikan University. Professor Akagi has received numerous scientific awards, including The Chemical Society of Japan (CSJ) Award.